Actinium (Ac)
Isotopes of Actinium
Isotope | Atomic Mass | Half-life | Mode of Decay | Nuclear Spin | Nuclear Magnetic Moment |
Ac-224 | 224.021708 | 2.7 hours | β- to Th-224; α to Fr-220; EC to Ra-224 |
0 | No data available |
Ac-225 | 225.02322 | 10.0 days | α to Fr-221 | 3/2 | No data available |
Ac-226 | 226.026089 | 1.224 days | β- to Th-226; α to Fr-222; EC to Ra-226 |
1 | No data available |
Ac-227 | 227.027750 | 21.77 years | β- to Th-228; α to Fr-224 |
3/2 | 1.1 |
Ac-228 | 228.031104 | 6.15 hours | β- to Th-229 | 3 | No data available |
Ac-229 | 229.03293 | 1.04 hours | No data available | 3/2 | No data available |
Actinium was discovered in 1899 by André-Louis Debierne. Its name derives from the Greek word aktinos, meaning "ray."
Actinium is a silvery metal with a cubic crystal form. It behaves like lanthanum, forming mostly the trivalent salts of the metal. It is strongly electropositive, the first ionization potential being 5.17 eV. It reacts with HCl, forming AcCl3, and also reacts with organic acids, forming their corresponding salts. Combustion in air can produce oxide and nitride. It is also susceptible to react with CO2, forming carbonate. It is used in nuclear reactors as a source of neutrons. Exposure to its radiation can cause cancer.
Properties of Actinium
Name | Actinium |
Symbol | Ac |
Atomic number | 89 |
Atomic weight | 227 |
Standard state | Solid at 298 ºK |
CAS Registry ID | 7440-34-8 |
Group in periodic table | N/A |
Group name | Actinoids |
Period in periodic table | 7 (Actinoid) |
Block in periodic table | f-block |
Color | Silvery |
Classification | Metallic |
Melting point | 1050 ºC |
Boiling point | 3300 °C |
Vaporization point | 3198 ºC |
Thermal conductivity | 12 (estimate) W/(m·K) |
Electronegativity | 1.1 |
Heat of vaporization | 400 kJ·mol-1 |
Heat of fusion | 14 kJ·mol-1 |
Density of solid | 10.07 g/cm3 |
Electron configuration | [Rn]6d17s2 |
Oxidation state | +3 |
Research
- Spectroscopic and computational investigation of actinium coordination chemistry
- Towards high-resolution laser ionization spectroscopy of the heaviest elements in supersonic gas jet expansion
- Octadentate picolinic acid-based bispidine ligand for radiometal ions
- An Eighteen-Membered Macrocyclic Ligand for Actinium-225 Targeted Alpha Therapy
- Simultaneous Separation of Actinium and Radium Isotopes from a Proton Irradiated Thorium Matrix
- Targeted Alpha Therapy, an Emerging Class of Cancer Agents: A Review
- Ultra-selective ligand-driven separation of strategic actinides