Uranium (U)
Isotopes of Uranium
Isotope | Atomic Mass | Half-life | Mode of Decay | Nuclear Spin | Nuclear Magnetic Moment |
U-230 | 230.03393 | 20.80 days | α to Th-226 | 0 | No data available |
U-231 | 231.03626 | 4.20 days | α to Th-227 | 5/2 | No data available |
U-232 | 232.03715 | 68.90 years | α to Th-228 | 0 | No data available |
U-233 | 233.039628 | 1.59 x 105 years | α to Th-229; SF | 5/2 | 0.59 |
U-234 | 234.0409468 | 2.45 x 105 years | α to Th-230; SF | 0 | No data available |
U-235 | 235.0439242 | 7.04 x 108 years | α to Th-231; SF | 7/2 | 0.38 |
U-236 | 236.045561 | 2.34 x 107 years | α to Th-232; SF | 0 | No data available |
U-237 | 237.048723 | 6.75 days | β- to Np-237 | 1/2 | No data available |
U-238 | 238.0507847 | 4.46 x 109 years | α to Th-234; SF | 0 | No data available |
Uranium was discovered in 1789 by Martin Heinrich Klaproth and named after the planet Uranus, which had just been discovered. It was isolated in 1841 by Eugène-Melchior Péligot, and its radioactive properties were discovered in 1896 by Henri Becquerel.
The heaviest naturally-occurring element, uranium is a silvery-white metal that is malleable, ductile and slightly paramagnetic. The metal exists in three crystal forms: an orthorhombic alpha phase with a density of 18.97 g/cm3 and stable up to 667 ºC, a tetragonal beta phase with density of 18.11 g/cm3 and stable from 688-776 ºC, and a body-centered cubic form with a density of 18.06 g/cm3 and stable in the range of 776-1132 ºC. It is insoluble in water and alkalis and soluble in acids. Uranium metal reacts with almost all nonmetallic elements and their compounds, its reactivity increasing with temperature. Hydrochloric and nitric acids dissolve uranium, but non-oxidizing acids other than hydrochloric acid attack the element very slowly. When finely divided, it can react with cold water; in air, uranium metal becomes coated with a dark layer of uranium oxide. Uranium in ores is extracted chemically and converted into uranium dioxide or other chemical forms usable in industry.
The major application of uranium in the military sector is in high-density penetrators. This ammunition consists of depleted uranium (DU) alloyed with 1–2% other elements. Depleted uranium is also used as a shielding material in some containers that store and transport radioactive materials. Uranium-235 has been used as the fissile explosive material to produce nuclear weapons. The main use of uranium in the civilian sector is to fuel nuclear power plants: one kilogram of Uranium-235 can theoretically produce as much energy as 3000 tonnes of coal. Uranium has also been used in small amounts for yellow glass and pottery glazes, such as uranium glass and in Fiesta® dinnerware.
Uranium is a toxic metal. Exposure can affect kidneys, brain, liver, heart and other systems. The metal is commonly handled with gloves as a precaution; uranium concentrate is handled and contained in order to prevent its inhalation or ingestion.
Properties of Uranium
Name | Uranium |
Symbol | U |
Atomic number | 92 |
Atomic weight | 238.02891 |
Standard state | Solid at 298 ºK |
CAS Registry ID | 7440-61-1 |
Group in periodic table | N/A |
Group name | Actinoid |
Period in periodic table | 7 (Actinoid) |
Block in periodic table | f-block |
Color | Metallic gray |
Classification | Metallic |
Melting point | 1132.2 °C |
Boiling point | 3900 °C |
Vaporization point | 4131 °C |
Thermal conductivity | 27.6 W/(m·K) |
Electrical resistivity | 28 x 10-8 Ω·m |
Electronegativity | 1.38 |
Heat of vaporization | 420 kJ·mol-1 |
Heat of fusion | 14 kJ·mol-1 |
Density of liquid | 17.3 g/cm3 at 1132.2 °C |
Density of solid | 19.05 g/cm3 |
Electron configuration | [Rn]5f36d17s2 |
Ionic radii | U3+: 1.03 Å, U4+: 0.89 Å, U5+: 0.76 Å (coordination number 6); U6+: 0.45 Å (coordination number 2); U6+: 0.81 Å (coordination number 7) |
Oxidation states | +2, +3, +4, +4, +5, +6 |
Research
- Improving precision and accuracy of isotope ratios from short transient Laser Ablation – Multi-Collector-ICPMS signals: application to micron-size uranium particles
- Isotope geochemistry and revised geochronology of the Purrido Ophiolite (Cabo Ortegal Complex, NW Iberian Massif): Devonian magmatism with mixed sources and involved Mesoproterozoic basement
- Measurement of uranium isotope ratios in keratinous materials; a non-invasive bioassay for special nuclear material
- Regolith evolution on the millennial timescale from combined U–Th–Ra isotopes and in situ cosmogenic 10Be analysis in a weathering profile (Strengbach catchment, France)
- Isotope ratio characteristics and sensitivity for uranium determinations using a liquid sampling-atmospheric pressure glow discharge ion source coupled to an Orbitrap mass analyzer
- Ocean mixing and ice-sheet control of seawater 234U/238U during the last deglaciation
- Determination of the isotopic composition of micrometric uranium particles by UV femtosecond laser ablation coupled with sector-field single-collector ICP-MS
- Disequilibrium of naturally occurring radioactive materials (NORM) in drill cuttings from a horizontal drilling operation
- Reinterpretation of oceanic 230Th profiles based on decadal export productivity (2003–2010)
- Geochemical, isotopic, and zircon (U-Pb, O, Hf isotopes) evidence for the magmatic sources of the volcano-plutonic Ollo de Sapo Formation, Central Iberia
- Paleoclimate and vegetation of the Last Glacial Cycles in Jerusalem from a Speleothem Record
- Palaeolithic cave art in Borneo
- A new species of Homo from the Late Pleistocene of the Philippines