Bismuth (Bi)
Stable Isotopes of Bismuth
Isotope | Z(p) | N(n) | Atomic Mass | Natural Abundance | Nuclear Spin |
Bi-209 | 83 | 126 | 208.980384 | 100.00% | 9/2- |
In early times, bismuth was often confused with tin and lead because of its similarities to those elements. In 1753, Claude Geoffroy the Younger demonstrated its distinctness from lead. It takes its name from the German word bisemutum.Miners in the age of alchemy also gave bismuth the name tectum argenti, or “silver being made,” in the sense of silver still in the process of being formed within the earth.
Bismuth is a crystalline, brittle, soft metal, grayish-white with a pinkish tinge and a metallic luster. It has a rhombohedral crystal system. It is soluble in nitric and hydrochloric acids. Its thermal conductivity is lowest of all metals except mercury. It forms trivalent and pentavalent compounds (the trivalent compounds are more common). Many of bismuth's chemical properties are similar to those of other elements in its group, especially arsenic and antimony. It is stable in both dry and moist air at ordinary temperatures; at elevated temperatures, the vapors of the metal combine rapidly with oxygen, forming bismuth trioxide. Bismuth reacts with chlorine, bromine and iodine vapors, forming their bismuth halides.
The major commercial applications of bismuth are as fusible alloys and in pharmaceuticals. Some bismuth compounds also find catalytic applications in the manufacture of acrylic fibers. It is used in electric fuses, fusible boiler plugs, low-melting solders, thermoelectric materials and semiconductors, and as an additive to steel and other metals. Other compounds are used in medicine as antacids, antisyphilitics and anti-infectives, and in cosmetics such as lipstick, powder and eye shadow.
Properties of Bismuth
Name | Bismuth |
Symbol | Bi |
Atomic number | 83 |
Atomic weight | 208.98 |
Standard state | Solid at 298 °K |
CAS Registry ID | 7440-69-9 |
Group in periodic table | 15 |
Group name | Pnictogen |
Period in periodic table | 6 |
Block in periodic table | p-block |
Color | Lustrous reddish-white |
Classification | Metallic |
Melting point | 271 °C |
Boiling point | 1560 °C |
Vaporization point | 1564 ºC |
Thermal conductivity | 8 W/(m·K) |
Electrical resistivity | 106.8 µΩ·cm at 0 °C |
Electronegativity | 1.67 |
Specific heat | 122 J/(kg·K) |
Heat of vaporization | 160 kJ·mol-1 |
Heat of fusion | 10.9 kJ·mol-1 |
Density of liquid | 10.05 g/cm3 at 271 °C |
Density of solid | 9.79 g/cm3 |
Electron configuration | [Xe]4f145d106s26p3 |
Atomic radius | 1.88 Å (coordination number 12) |
Atomic volume | 21.3 cm3/g-atom |
Ionic radii in crystals corresponding to coordination number 6 | Bi3+: 1.03 Å; Bi5+: 0.76 Å |
Ionization potentials | Bi(+3) 25.56 eV and Bi(+5) 56.0 eV |
Electron affinity | 0.946 eV |
Oxidation states | +3, +5 |