Plutonium (Pu)
Isotopes of Plutonium
Isotope | Atomic Mass | Half-life | Mode of Decay | Nuclear Spin | Nuclear Magnetic Moment |
Pu-236 | 236.04605 | 2.87 years | α to U-232; SF |
0 | No data available |
Pu-237 | 237.04840 | 45.70 days | EC to Np-237; α to U-232 |
7/2 | No data available |
Pu-238 | 238.04955 | 87.74 years | α to U-234; SF |
0 | No data available |
Pu-239 | 239.05216 | 24,110 years | α to U-235; SF |
1/2 | 0.203 |
Pu-240 | 240.05381 | 6537 years | α to U-236; SF |
0 | No data available |
Pu-241 | 241.05684 | 14.40 years | α to U-237; SF; ß- to Am-241 |
5/2 | -0.683 |
Pu-242 | 242.05874 | 3.76 x 105 years | α to U-238; SF | 0 | No data available |
Pu-243 | 243.06200 | 4.956 hours | ß- to Am-243 | 7/2 | No data available |
Pu-244 | 244.064199 | 8.20 x 107 years | α to U-240; SF | 0 | No data available |
Pu-245 | 245.06774 | 10.50 hours | ß- to Am-245 | 9/2 | No data available |
Pu-246 | 246.07020 | 10.85 days | ß- to Am-246 | 0 | No data available |
Plutonium, named for the planet Pluto, is the second transuranium element of the actinide series to have been discovered. It was synthesized in 1940 by Glenn T. Seaborg, Joseph William Kennedy, Edward M. McMillan and Arthur C. Wahl in a cyclotron in Berkeley, California, USA.
Plutonium, like most metals, has a bright silvery appearance at first, much like nickel, but it oxidizes very quickly to a dull gray, although yellow and olive green are also reported. At room temperature plutonium is in its α form (alpha). This, the most common allotrope of the element, is about as hard and brittle as grey cast iron unless it is alloyed with other metals to make it soft and ductile. Unlike most metals, plutonium is not a good conductor of heat or electricity. It is a reactive metal. In moist air or moist argon, it oxidizes rapidly, producing a mixture of oxides and hydrides. Plutonium can also form alloys and intermediate compounds with most other metals.
Twenty radioactive isotopes of plutonium have been characterized. The longest-lived are Plutonium-244, with a half-life of about 80.8 million years; Plutonium-242, with a half-life of about 373,300 years; and Plutonium-239, with a half-life of 24,110 years. All of the remaining radioactive isotopes have half-lives that are less than 7,000 years. Of great importance is Plutonium-239, one kilogram of which provides the equivalent of nearly 22 million kilowatt hours of heat energy. The complete detonation of a kilogram of plutonium produces an explosion equal to that of about 20,000 tons of chemical explosive.
Practical applications of plutonium include nuclear weaponry, electrical power generation, spacecraft power sources, artificial heart pacemakers and scientific research.
Isotopes and compounds of plutonium are radioactive and accumulate in bone marrow. Acute or longer-term exposure can carry a danger of serious health outcomes including radiation sickness, genetic damage, cancer and death. The danger increases with the amount of exposure.
Properties of Plutonium
Name | Plutonium |
Symbol | Pu |
Atomic number | 94 |
Atomic weight | [244] |
Standard state | Solid at 298 °K |
CAS Registry ID | 7440-07-5 |
Group in periodic table | N/A |
Group name | Actinoid |
Period in periodic table | 7 (Actinoid) |
Block in periodic table | f-block |
Color | Silvery white |
Classification | Metallic |
Melting point | 912.5 °K [or 639.4 °C or 1182.9 °F] |
Boiling point | 3503 °K [or 3230 °C or 5846 °F] |
Density of solid | 19.82 g/cm3 |
Electron configuration | [Rn]5f67s2 |